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Tolylfluanid

PESTANAL®, analytical standard

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About This Item

Empirical Formula (Hill Notation):
C10H13Cl2FN2O2S2
CAS Number:
731-27-1
Molecular Weight:
347.26
Colour Index Number:
45430
Beilstein/REAXYS Number:
2949607
EC Number:
211-986-9
MDL number:
MFCD00055477
UNSPSC Code:
41116107
PubChem Substance ID:
329753720
NACRES:
NA.24

grade

analytical standard

Quality Level

100

product line

PESTANAL®

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

application(s)

agriculture
environmental

format

neat

SMILES string

CN(C)S(=O)(=O)N(SC(F)(Cl)Cl)c1ccc(C)cc1

InChI

1S/C10H13Cl2FN2O2S2/c1-8-4-6-9(7-5-8)15(18-10(11,12)13)19(16,17)14(2)3/h4-7H,1-3H3

InChI key

HYVWIQDYBVKITD-UHFFFAOYSA-N

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General description

Tolylfluanid is a phenylsulfamide fungicide, generally used in fertilizers. It can also be used as an antifouling agent in vessel paints.

Application

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.
Tolylfluanid may be used as a reference standard for the determination of the analyte in nutraceutical formulations using dispersive liquid-liquid microextraction(DLLME) coupled with gas chromatography-mass spectrometry method.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

signalword

Danger

Hazard Classifications

Acute Tox. 2 Inhalation - Aquatic Acute 1 - Eye Irrit. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT RE 1 - STOT SE 3

target_organs

Respiratory system

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges

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Certificates of Analysis (COA)

Lot/Batch Number
BCCJ3200
BCCB7968
BCBZ7089
BCBT9907
SZBD038XV

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Sigma-Aldrich

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Dispersive liquid-liquid microextraction followed by gas chromatography- mass spectrometry for the determination of pesticide residues in nutraceutical drops.
Szarka A, et al.
Journal of Chromatography A, 1570(1), 126-134 (2018)
Ali Kadar et al.
Journal of chromatography. B, Analytical technologies in the biomedical and life sciences, 1113, 69-76 (2019-03-23)
In this study, an accurate and robust gas chromatography/mass spectrometry method was developed for quantitative analysis of diphenylamine, tolylfluanid, propargite and phosalone in liver fractions. Different injector parameters were optimized by an experimental design technique (central composite design). An optimal
Aurélie Berthet et al.
Toxicology letters, 324, 38-45 (2020-02-18)
Tolylfluanid (TF) is a sensitizing biocide used in antifouling products and wood preservatives. Paint application is associated with skin exposure; however, the importance of this exposure route is uncertain as TF skin permeation rates are lacking in the peer-reviewed scientific
Increase in intracellular Ca2+ level by phenylsulfamide fungicides, tolylfluanid and dichlofluanid, in rat thymic lymphocytes.
Fukunaga E, et al,
Environmental Toxicology and Pharmacology, 40(1), 149- 155 (2015)
S Gielen et al.
Communications in agricultural and applied biological sciences, 71(2 Pt A), 79-82 (2007-03-30)
The use of Euparen Multi (tolylfluanid) for controlling Botrytis cinerea in tomatoes has been decreased the last decade for several reasons. Because of the lack of different fungicides with a good efficacy it is important that growers can use different
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