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33398

Supelco

Bromocyclen

PESTANAL®, analytical standard

Synonym(s):

5- Bromomethyl-1,2,3,4,7,7-hexachloro-2-norbornene

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About This Item

Empirical Formula (Hill Notation):
C8H5BrCl6
CAS Number:
Molecular Weight:
393.75
EC Number:
MDL number:
UNSPSC Code:
41116107
PubChem Substance ID:
NACRES:
NA.24

grade

analytical standard

Quality Level

product line

PESTANAL®

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable
NMR: suitable
gas chromatography (GC): suitable

suitability

passes test for identity (NMR)

application(s)

agriculture
environmental

format

neat

SMILES string

ClC1=C(Cl)C2(Cl)C(CBr)CC1(Cl)C2(Cl)Cl

InChI

1S/C8H5BrCl6/c9-2-3-1-6(12)4(10)5(11)7(3,13)8(6,14)15/h3H,1-2H2

InChI key

DAASOABUJRMZAD-UHFFFAOYSA-N

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General description

Bromocyclen is a cyclodiene insecticide and has been used widely against ectoparasites for treating domestic animals.

Application

Bromocyclen may be used as a reference standard for the determination of bromocyclen in fish tissue samples using solid-phase microextraction coupled to gas chromatography with ECD and ICP–MS detection.
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

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Find a digital Reference Material for this product available on our online platform ChemisTwin® for NMR. You can use this digital equivalent on ChemisTwin® for your sample identity confirmation and compound quantification (with digital external standard). An NMR spectrum of this substance can be viewed and an online comparison against your sample can be performed with a few mouseclicks. Learn more here and start your free trial.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

wgk_germany

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)


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Bromocyclen contamination of surface water, waste water and fish from northern Germany, and gas chromatographic chiral separation.
Bethan B, et al.
Chemosphere, 34(11), 2271-2280 (1997)
Treatment for bromocyclen poisoning.
M J Priest
The Veterinary record, 127(9), 243-244 (1990-09-01)
M P Quick
Veterinary and human toxicology, 34(5), 455-457 (1992-10-01)
This report summarizes the case histories and tabulates the analytical results from investigations of 8 incidents of suspected bromocyclen poisoning. Interpretation of the results and withdrawal of ALUGAN from the UK market are discussed.
Natalia Fidalgo-Used et al.
Talanta, 75(3), 710-716 (2008-07-01)
A method for enantioselective determination of bromocyclen enantiomers in fish tissue has been developed. The enantiomers were resolved by capillary gas chromatography (GC) using a commercial chiral column (CP-Chirasil-Dex CB) and a temperature program from 50 degrees C (held for

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