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Metsulfuron-methyl

PESTANAL®, analytical standard

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About This Item

Empirical Formula (Hill Notation):
C14H15N5O6S
CAS Number:
74223-64-6
Molecular Weight:
381.36
Beilstein/REAXYS Number:
587472
MDL number:
MFCD00128061
UNSPSC Code:
41116107
PubChem Substance ID:
329757180
NACRES:
NA.24

grade

analytical standard

Quality Level

100

product line

PESTANAL®

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

application(s)

agriculture
environmental

format

neat

SMILES string

COC(=O)c1ccccc1S(=O)(=O)NC(=O)Nc2nc(C)nc(OC)n2

InChI

1S/C14H15N5O6S/c1-8-15-12(18-14(16-8)25-3)17-13(21)19-26(22,23)10-7-5-4-6-9(10)11(20)24-2/h4-7H,1-3H3,(H2,15,16,17,18,19,21)

InChI key

RSMUVYRMZCOLBH-UHFFFAOYSA-N

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General description

Metsulfuron-methyl belongs to the class of post-emergent, low-application-rate sulfonylurea herbicides. It is used in cereals and other row crops for protection against broad-leaved weeds and some grasses.

Application

Metsulfuron-methyl may be used as an analytical reference standard for the determination of the analyte in water samples and environmental samples by various chromatography techniques.
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Recommended products

Find a digital Reference Material for this product available on our online platform ChemisTwin® for NMR. You can use this digital equivalent on ChemisTwin® for your sample identity confirmation and compound quantification (with digital external standard). An NMR spectrum of this substance can be viewed and an online comparison against your sample can be performed with a few mouseclicks. Learn more here and start your free trial.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

pictograms

Environment
GHS09

signalword

Warning

hcodes

H410

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1

Storage Class

11 - Combustible Solids

wgk_germany

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
BCCD9696
BCBW9108
BCBV5730
SZBF054XV
SZBF045XV

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Persistence of metsulfuron-methyl in wheat crop and soil.
Sondhia S
Environmental Monitoring and Assessment, 147(1-3), 463-469 (2008)
Preconcentration and determination of nicosulfuron, thifensulfuron-methyl and metsulfuron-methyl in water samples using carbon nanotubes packed cartridge in combination with high performance liquid chromatography.
Zhou Q, et al.
Analytica Chimica Acta, 559(2), 200-206 (2006)
Determination and quantitation of ten sulfonylurea herbicides in soil samples using liquid chromatography with electrospray ionization mass spectrometric detection.
Guibiao Y, et al.
Chinese Journal of Analytical Chemistry, 34(2-3), 1207-1212 (2006)
Nan-Xi Wang et al.
Chemosphere, 86(11), 1098-1105 (2012-01-06)
Tribenuron methyl (TBM) is a member of the sulfonylurea herbicide family and is widely used in weed control. Due to its phytotoxicity to rotating-crops, concerns on TBM-pollution to soil have been raised. In this study, experimental results indicated that microbial
R Bossi et al.
Journal of chromatography. A, 957(1), 27-36 (2002-07-10)
A new LC-MS-MS method for analysis of rainwater has been developed and validated for 53 pesticides, degradation products of pesticides and selected nitrophenols. The method was used to monitor the concentration of pesticides in rainwater at one location near Roskilde
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