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Supelco

Tetrahexylammonium hydrogensulfate

suitable for ion pair chromatography, LiChropur™, ≥99.0% (T)

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About This Item

Linear Formula:
[CH3(CH2)5]4N(HSO4)
CAS Number:
32503-34-7
Molecular Weight:
451.75
Beilstein/REAXYS Number:
4629729
EC Number:
251-069-0
MDL number:
MFCD00037675
UNSPSC Code:
12000000
PubChem Substance ID:
329769575
NACRES:
NB.21

description

cationic

Quality Level

100

assay

≥99.0% (T)

form

crystals

quality

LiChropur™

technique(s)

ion pair chromatography: suitable

mp

98-100 °C (lit.)
99-102 °C

λ

10 % in acetonitrile

UV absorption

λ: 210 nm Amax: 0.10
λ: 220 nm Amax: 0.04
λ: 230 nm Amax: 0.03
λ: 260 nm Amax: 0.02
λ: 500 nm Amax: 0.02

suitability

corresponds to standard for RP gradient test
corresponds to standard for filter test

SMILES string

OS([O-])(=O)=O.CCCCCC[N+](CCCCCC)(CCCCCC)CCCCCC

InChI

1S/C24H52N.H2O4S/c1-5-9-13-17-21-25(22-18-14-10-6-2,23-19-15-11-7-3)24-20-16-12-8-4;1-5(2,3)4/h5-24H2,1-4H3;(H2,1,2,3,4)/q+1;/p-1

InChI key

RULHPTADXJPDSN-UHFFFAOYSA-M

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General description

Tetrahexylammonium hydrogensulfate is a quaternary ammonium salt mainly used as an electrolyte.

Application

Tetrahexylammonium hydrogensulfate may have been used as a phase-transfer catalyst during catalysis analysis of benzylic halide to carboxylic acid.

Legal Information

LiChropur is a trademark of Merck KGaA, Darmstadt, Germany

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

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Selective phase transfer and palladium (0)-catalyzed carbonylation, carbalkoxylation, and reduction reactions.
Alper, Howard, Khaled Hashem, and Josef Heveling.
Organometallics, 1.6, 775-778 (1982)
The effects of tetrahexylammonium chloride on calcium mobilization from cerebellar microsomes.
L G Sayers et al.
Biochemical Society transactions, 21(2), 105S-105S (1993-05-01)
Masamichi Yamanaka et al.
Journal of the American Chemical Society, 126(9), 2939-2943 (2004-03-05)
Resorcinarene 1b forms a hexameric assembly in water-saturated CDCl(3) that encapsulates one tetraalkylammonium salt (2(+)Br(-)). The remaining space is occupied by coencapsulated solvent molecules. A maximum of three and minimum of one CHCl(3) molecule were found inside of capsules with
Zeynep S Teksin et al.
Journal of controlled release : official journal of the Controlled Release Society, 116(1), 50-57 (2006-10-20)
Parallel Artificial Membrane Permeability Assay (PAMPA) is a method to screen drug candidates for membrane permeability. The objective was to characterize the transport of a model weak base, metoprolol, across a three lipid-component PAMPA system (denoted A-PAMPA, for anionic-PAMPA) and
Huiyu Zhou et al.
Journal of pharmaceutical sciences, 91(6), 1502-1511 (2002-07-13)
Inhalation therapy for infectious lung diseases, such as tuberculosis, is currently being explored, with microspheres being used to target alveolar macrophages. One method of drug encapsulation into polymeric microspheres to form hydrophobic ion-paired (HIP) complexes, and then coprecipitate the complex
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