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902225

Ir[dFMeppy]2-(4,4′-dCF3bpy)PF6

≥95%

Synonym(s):

Photocatalyst

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About This Item

Empirical Formula (Hill Notation):
C36H22F16IrN4P
Molecular Weight:
1037.75
UNSPSC Code:
41141700

assay

≥95%

form

powder

reaction suitability

core: iridium
reaction type: Photocatalysis
reagent type: catalyst

mp

>300 °C

Related Categories

Application

Under a dual catalytic copper/photoredox manifold, the Mes-Umemoto reagent has been demonstrated to be an excellent photocatalyst for the trifluoromethylation of alkyl halides and aryl halides to yield alkyl-CF3 and aryl-CF3 in high yields. In both cases, these reactions exhibit wide substrate scope with good functional group tolerance. More specifically, a variety of 5-membered and 6-membered heteroaryl halides can be readily converted to the corresponding trifluoromethylheteroarenes under mild conditions. For trifluoromethylation reactions, use with dMesSCF3 (901466) and supersilanol (902489).

Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

Other Notes

A radical approach to the copper oxidative addition problem:Trifluoromethylation of bromoarenes

related product

Product No.
Description
Pricing

747769

[Ir(dtbbpy)(ppy)2]PF6

747793

(Ir[dF(CF3)ppy]2(dtbpy))PF6

804215

[Ir{dFCF3ppy}2(bpy)]PF6

900540

Ir(dFppy)3

900539

Ir[p-F(t-Bu)-ppy]3

900538

Ir(p-F-ppy)3

900579

(S)-2-Benzylpiperidine, ≥95%

901466

Mes-Umemoto reagent, ≥95%

901368

[Ir(dFppy)2(dtbbpy)]PF6

901409

[Ir(dF(Me)ppy)2(dtbbpy)]PF6

902217

Ir[dFFppy]2-(4,4′-dCF3bpy)PF6, ≥95%

902489

Tris(trimethylsilyl)silanol, ≥95%

904694

Ir(p-CF3-ppy)3, ≥95%

905518

Ir(dFFppy)2(dtbbpy)PF6

905917

(Ir[Me(Me)ppy]2(dtbpy))PF6

908568

[Ir(dFCF3ppy)2-(5,5′-dCF3bpy)]PF6, ≥95%

908703

[Ir(p-F(Me)ppy)2-(4,4′-dtbbpy)]PF6, ≥95%

911607

[Ir(dFOMeppy)2-(5,5′-dCF3bpy)]PF6 , ≥95%

912948

Ir[FCF3(CF3)ppy]2(dtbbpy)PF6

922897

[Ir(ppy)2(5,5′-Me2bpy)]PF6, ≥95%

925497

[Ir(dFOMeppy)2(dtbbpy)]PF6, ≥95%

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

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[Ir(dtbbpy)(ppy)2]PF6

Sigma-Aldrich

747769

[Ir(dtbbpy)(ppy)2]PF6

[Ir(dFCF3ppy)2-(5,5’-dCF3bpy)]PF6 ≥95%

Sigma-Aldrich

908568

[Ir(dFCF3ppy)2-(5,5′-dCF3bpy)]PF6

Ir(p-CF3-ppy)3 ≥95%

Sigma-Aldrich

904694

Ir(p-CF3-ppy)3

[Ir(p-F(Me)ppy)2-(4,4′-dtbbpy)]PF6 ≥95%

Sigma-Aldrich

908703

[Ir(p-F(Me)ppy)2-(4,4′-dtbbpy)]PF6

Ir(dFppy)3

Sigma-Aldrich

900540

Ir(dFppy)3

Ir[p-F(t-Bu)-ppy]3

Sigma-Aldrich

900539

Ir[p-F(t-Bu)-ppy]3

Ir(p-F-ppy)3

Sigma-Aldrich

900538

Ir(p-F-ppy)3

[Ru(bpz)3][PF6]2 95%

Sigma-Aldrich

747777

[Ru(bpz)3][PF6]2

Chip Le et al.
Science (New York, N.Y.), 360(6392), 1010-1014 (2018-06-02)
Transition metal-catalyzed arene functionalization has been widely used for molecular synthesis over the past century. In this arena, copper catalysis has long been considered a privileged platform due to the propensity of high-valent copper to undergo reductive elimination with a

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