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936669

Sigma-Aldrich

DPPF ChemBeads

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Synonym(s):

DPPF, 1,1′-Bis(diphenylphosphino)ferrocene ChemBeads, 1,1′-Ferrocenediyl-bis(diphenylphosphine) ChemBeads, 1,1′-Ferrocenediyl-bis(diphenylphosphine), dppf

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About This Item

Empirical Formula (Hill Notation):
C34H28FeP2
CAS Number:
12150-46-8
Molecular Weight:
554.38
MDL number:
MFCD00001422
UNSPSC Code:
12352100

form

solid

Quality Level

100

composition

loading, 4-6 wt. %

mp

181-182 °C (dec.) (lit.)

SMILES string

[Fe].[CH]1[CH][CH][C]([CH]1)P(c2ccccc2)c3ccccc3.[CH]4[CH][CH][C]([CH]4)P(c5ccccc5)c6ccccc6

InChI

1S/2C17H14P.Fe/c2*1-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;/h2*1-14H;

InChI key

HPXNTHKXCYMIJL-UHFFFAOYSA-N

General description

The ChemBeads product of the 1,1′-Bis(diphenylphosphino)ferrocene (DPPF) ligand. DPPF is a bis-phosphine ligand bearing two diphenylphosphine moieties with a ferrocene backbone. Loaded on glass beads for use in high-throughput expermentation (HTE).

Application

  • DPPF has been used as a ligand in:
  • The ruthenium catalyzed N-alkylation of amines and sulfonamides using borrowing hydrogen methodology.[1] (19191700)
  • The cooperative Cu/Pd catalyzed borylallenylation of trifluoromethyl-1,3-enynes to generate conjugated bisallenes.[2] (36321461)
  • The cooperative Cu/Pd catlyzed borocarbonylation of ethylene.[3] (36226440)
  • The gold catalyzed synthesis of 2-phosphoryl indolin-3-ones.[4] (35815915)
  • The iron-catalyzed vinylzincation of terminal alkynes.[5] (34935372) ChemBeads are chemical coated glass beads. ChemBeads offer improved flowability and chemical uniformity perfect for automated solid dispensing and high-throughput experimentation. The method of creating ChemBeads uses no other chemicals or surfactants allowing the user to accurately dispense sub-milligram amounts of chemical.
  • For general uses, product is also available in powdered form (177261)

related product

Product No.
Description
Pricing

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

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