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T0886

Sigma-Aldrich

Triethylamine

≥99%

Synonym(s):

TEA, N,N-Diethylethanamine

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About This Item

Linear Formula:
(C2H5)3N
CAS Number:
Molecular Weight:
101.19
Beilstein/REAXYS Number:
605283
EC Number:
MDL number:
UNSPSC Code:
12352116
PubChem Substance ID:
NACRES:
NA.21

vapor density

3.5 (vs air)

Quality Level

vapor pressure

51.75 mmHg ( 20 °C)

assay

≥99%

autoignition temp.

593 °F

shelf life

3 yr

expl. lim.

8 %

impurities

≤0.5% water (Karl Fischer)

refractive index

n20/D 1.401 (lit.)

bp

88.8 °C (lit.)

mp

−115 °C (lit.)

density

0.726 g/mL at 25 °C (lit.)

SMILES string

CCN(CC)CC

InChI

1S/C6H15N/c1-4-7(5-2)6-3/h4-6H2,1-3H3

InChI key

ZMANZCXQSJIPKH-UHFFFAOYSA-N

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Application

Triethylamine has been used:
  • as a hydrogen donor for the polymerization of various monomers
  • to catalyze silanization
  • in the synthesis of the Cy3-Alexa647 heterodimer
  • in the synthesis of methacrylated solubilized decellularized cartilage

Biochem/physiol Actions

Triethylamine is known to drive polymerization reaction. It acts as a source of carbon and nitrogen for bacterial cultures. Triethylamine is used in pesticides. Triethylamine can serve as an organic solvent.

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suggested gloves for splash protection

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Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1A - STOT SE 3

target_organs

Respiratory system

wgk_germany

WGK 1

flash_point_f

closed cup

flash_point_c

closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


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Triethylamine United States Pharmacopeia (USP) Reference Standard

USP

1683559

Triethylamine

Synthesis and characterization of poly(vinylchloride) type macrophotoinitiator comprising side-chain thioxanthone via click chemistry
Akat H and Ozkan M
Express Polymer Letters, 5(4), 318?326-318?326 (2011)
Wide-field in vivo background free imaging by selective magnetic modulation of nanodiamond fluorescence.
Sarkar SK, et al.
Biomedical Optics Express, 5(4), 1190-1202 (2014)
The biodegradation pathway of triethylamine and its biodegradation by immobilized Arthrobacter protophormiae cells
Cai T, et al.
Journal of Hazardous Materials, 186(1), 59-66 (2011)
RESOLFT nanoscopy with photoswitchable organic fluorophores.
Kwon J, et al.
Scientific reports (2015)
States of Water Located in the Continuous Organic Phase of 1?Butyl?3?methylimidazolium Tetrafluoroborate/Triton X-100/Triethylamine Reverse Microemulsions
Na Li, et al.
ChemPhysChem (2007)

Articles

Amide bonds are ubiquitous in both nature and industrial applications. They are vital to the structure and function of biological macromolecules and polymers. The importance of this functionality has resulted in numerous approaches to its formation, ranging from stoichiometric activation of carboxylic acids to more recent advances in catalytic amide bond formation.

The Heck reaction is the palladium catalyzed cross-coupling reaction between alkenes and aryl or vinyl halides (or triflates) to afford substituted alkenes.

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

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