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269336

Sigma-Aldrich

Peracetic acid solution

32 wt. % in dilute acetic acid

Synonym(s):

Peroxyacetic acid

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About This Item

Linear Formula:
CH3CO3H
CAS Number:
Molecular Weight:
76.05
Beilstein/REAXYS Number:
1098464
MDL number:
UNSPSC Code:
12352106
PubChem Substance ID:

vapor pressure

20 mmHg ( 25 °C)

Quality Level

form

liquid

composition

acetic acid, 40-45%

reaction suitability

reagent type: oxidant

concentration

29.0-35% (by sodium thiosulfate, titration)
32 wt. % in dilute acetic acid

impurities

<6.0% hydrogen peroxide

refractive index

n20/D 1.3876

pH

<1

density

1.13 g/mL at 25 °C

shipped in

wet ice

storage temp.

2-8°C

SMILES string

CC(=O)OO

InChI

1S/C2H4O3/c1-2(3)5-4/h4H,1H3

InChI key

KFSLWBXXFJQRDL-UHFFFAOYSA-N

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General description

Peracetic acid (PAA) is a peroxy acid that is commonly used as an excellent oxidizing agent in organic synthesis. It is also used as a bleaching and sterilizing agent.

Application

Peracetic acid solution (32 wt. % in dilute acetic acid) can be used as an oxidant for the selective epoxidation of aliphatic terminal alkenes in the presence of manganese(II) perchlorate as the catalyst at ambient temperature. It is also used to oxidize sulfides, selenides, and amines.

Features and Benefits

  • Easily synthesized
  • Environmentally benign reagent

signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Flam. Liq. 3 - Met. Corr. 1 - Org. Perox. D - Skin Corr. 1 - STOT SE 3

target_organs

Respiratory system

wgk_germany

WGK 2

flash_point_f

132.8 °F

flash_point_c

56 °C


Certificates of Analysis (COA)

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Ultrasound-assisted MnO2 catalyzed homolysis of peracetic acid for phenol degradation: The assessment of process chemistry and kinetics.
Rokhina EV, et al.
Chemical Engineering Journal, 276, 91-96 (2015)
Eagleson M.
Concise Encyclopedia Chemistry, 894-894 (1994)
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Compressed collagen is a promising scaffold for corneal stroma analogue due to its facile incorporation of keratocytes while mimicking the mechanical niche of a native cornea with dense collagen fibrillar structures. However, it does not offer the sufficient biochemical niche
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Peracetic acid is a strong disinfectant with a wide spectrum of antimicrobial activity. Due to its bactericidal, virucidal, fungicidal, and sporicidal effectiveness as demonstrated in various industries, the use of peracetic acid as a disinfectant for wastewater effluents has been
Alberto Baggioli et al.
Physical chemistry chemical physics : PCCP, 15(4), 1130-1140 (2012-12-12)
We examine several computational strategies for the prediction of the (17)O-NMR shielding constants for a selection of organic acids and peracids in aqueous solution. In particular, we consider water (the solvent and reference for the chemical shifts), hydrogen peroxide, acetic

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