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Sigma-Aldrich

Cerium(IV) sulfate tetrahydrate

puriss. p.a., ≥98%

Synonym(s):

Ceric sulfate tetrahydrate

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About This Item

Linear Formula:
Ce(SO4)2 · 4H2O
CAS Number:
Molecular Weight:
404.30
EC Number:
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NA.21

vapor pressure

<0.01 hPa ( 20 °C)
<0.01 hPa ( 50 °C)

Quality Level

grade

puriss. p.a.

assay

≥98%

form

powder

reaction suitability

reagent type: catalyst
core: cerium

impurities

≤0.01% insoluble matter in dilute H2SO4

pH

~0.5 (20 °C, 207 g/L)

anion traces

chloride (Cl-): ≤10 mg/kg
phosphate (PO43-): ≤100 mg/kg

cation traces

Cu: ≤10 mg/kg
Fe: ≤50 mg/kg
Pb: ≤10 mg/kg

SMILES string

[Ce+4].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O

InChI

1S/Ce.2H2O4S/c;2*1-5(2,3)4/h;2*(H2,1,2,3,4)/q+4;;/p-4

InChI key

VZDYWEUILIUIDF-UHFFFAOYSA-J

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General description

Cerium(IV) sulfate tetrahydrate is a hydrated salt of cerium sulfate. Its molecule contains cerium ions coordinated with eight oxygen atoms. Its crystals have been reported to be orthorhombic.

Application

Cerium(IV) sulfate tetrahydrate may be employed in the synthesis of alkyl esters of oxo acids and oxo acids, via reaction with 2-substituted cycloalkanone. It may be used in the preparation of 0.01M cerium(IV) sulfate in 2M sulfuric acid solution.

pictograms

CorrosionEnvironment

signalword

Danger

hcodes

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Corr. 1B

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable


Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Oxidation of 2-Substituted Cycloalkanones with Cerium (IV) Sulfate Tetrahydrate in Alcohols and Acetic Acid.
He L and Horiuchi CA.
Bulletin of the Chemical Society of Japan, 72(11), 2515-2521 (1999)
Yasuyuki Miura et al.
Journal of chromatography. A, 956(1-2), 77-84 (2002-07-11)
Rapid separation and determination of mixtures of L-ascorbic acid, nitrite, sulfite, oxalate, iodide and thiosulfate by conventional ion chromatography is often difficult due to incomplete separation of L-ascorbic acid and nitrite from the water peak when using eluents giving short
The Crystal Structure of Cerium (IV) Sulfate Tetrahydrate.
Lindgren O.
Acta Chemica Scandinavica, Series A: Physical and Inorganic Chemistry, 31(6), 453-456 (1977)

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