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71640

Sigma-Aldrich

Sodium phosphate dibasic

puriss. p.a., ACS reagent, anhydrous, ≥99.0% (T)

Synonym(s):

sec-Sodium phosphate, Disodium hydrogen phosphate, Disodium phosphate, Sodium hydrogenphosphate

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About This Item

Linear Formula:
Na2HPO4
CAS Number:
7558-79-4
Molecular Weight:
141.96
EC Number:
231-448-7
MDL number:
MFCD00003496
UNSPSC Code:
12352300
eCl@ss:
38070211
PubChem Substance ID:
329763389
NACRES:
NA.21

grade

ACS reagent
puriss. p.a.

Quality Level

200

assay

≥99.0% (T)

form

powder (or crystals)

impurities

≤0.001% total nitrogen (N)

loss

≤0.2% loss on drying, 105 °C

pH

8.7-9.3 (25 °C, 50 mg/mL in H2O)

pKa (25 °C)

(1) 2.15, (2) 6.82, (3) 12.38 (phosphoric acid)

anion traces

chloride (Cl-): ≤10 mg/kg
sulfate (SO42-): ≤50 mg/kg

cation traces

Ca: ≤10 mg/kg
Cd: ≤5 mg/kg
Co: ≤5 mg/kg
Cr: ≤5 mg/kg
Cu: ≤5 mg/kg
Fe: ≤5 mg/kg
K: ≤50 mg/kg
Mg: ≤5 mg/kg
Mn: ≤5 mg/kg
Ni: ≤5 mg/kg
Pb: ≤5 mg/kg
Zn: ≤5 mg/kg
heavy metals: ≤0.001% (by ICP-OES)

SMILES string

[Na+].[Na+].[H]OP([O-])([O-])=O

InChI

1S/2Na.H3O4P/c;;1-5(2,3)4/h;;(H3,1,2,3,4)/q2*+1;/p-2

InChI key

BNIILDVGGAEEIG-UHFFFAOYSA-L

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General description

Sodium phosphate dibasic is a sodium salt of phosphoric acid. It is highly hygroscopic and water-soluble compound used as a texturizer, emulsifier, and buffer. It can also be used as a reagent in water softeners, cleaners, and boiler treatments process.
Sodium phosphate is widely used buffer in molecular biology, biochemistry, and chromatographic studies. It exists in three forms: monobasic (NaH2PO4), dibasic (Na2HPO4), and tribasic (Na3PO4). Monobasic and dibasic forms in varying ratios are commonly used to compose the neutral sodium phosphate buffer solution.

Application

Sodium phosphate dibasic can be used:
  • As an efficient and low-cost catalyst for the synthesis of 2-aminochrome by the reaction between aromatic aldehyde, malononitrile, and α- or β-naphthol under solvent-free conditions.
  • As a buffer in the synthesis of cyclic, acyclic enones and α, β-unsaturated aldehydes from trimethylsilyl enol ethers by using palladium as a catalyst and oxone as oxidant.
  • As an efficient catalyst in the synthesis of 3,4-dihydropyrano[3,2-c] chromenes from aldehydes, malononitrile and 4-hydroxycoumarin.
  • As a phosphorous precursor with the phosphoric acid in the synthesis of hydroxyapatite by precipitation method using anionic surfactant SDS (sodium dodefcyl sulfate).

Storage Class

13 - Non Combustible Solids

wgk_germany

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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