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442315

Supelco

2,4-Dimethylaniline

analytical standard

Synonym(s):

1-Amino-2,4-dimethylbenzene, 2,4-Xylidine, 4-Amino-m-xylene

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About This Item

Linear Formula:
(CH3)2C6H3NH2
CAS Number:
95-68-1
Molecular Weight:
121.18
Beilstein/REAXYS Number:
636243
EC Number:
202-440-0
MDL number:
MFCD00007738
UNSPSC Code:
12000000
PubChem Substance ID:
24867795

grade

analytical standard

vapor density

4.2 (vs air)

vapor pressure

0.16 mmHg ( 25 °C)

CofA

current certificate can be downloaded

autoignition temp.

860 °F

expl. lim.

7 %

packaging

ampule of 1000 mg

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

refractive index

n20/D 1.558 (lit.)

bp

218 °C (lit.)

mp

−14.3 °C (lit.)

density

0.98 g/mL at 25 °C (lit.)

application(s)

environmental

format

neat

storage temp.

2-30°C

SMILES string

Cc1ccc(N)c(C)c1

InChI

1S/C8H11N/c1-6-3-4-8(9)7(2)5-6/h3-5H,9H2,1-2H3

InChI key

CZZZABOKJQXEBO-UHFFFAOYSA-N

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General description

2,4-Dimethylaniline is a dark brown colored liquid, which is obtained as a final degradation product of amitraz, a formamide acaricide. It is an environmentally stable compound, which is found to be oncogenic, mutagenic and genotoxic in nature.

Application

2,4-Dimethylaniline can undergo oxidative degradation, to form a series of hydroxylated aromatic amines, in the presence of ultraviolet-visible light or hydrogen peroxide.
2,4-Dimethylaniline may be used as an analytical standard for the determination of the analyte in beeswax, honey, and environmental samples by various chromatography techniques.
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

signalword

Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Chronic 2 - STOT RE 2

Storage Class

6.1A - Combustible, acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk_germany

WGK 3

flash_point_f

208.4 °F - closed cup

flash_point_c

98 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Headspace solvent microextraction-gas chromatographic thermionic specific detector determination of amitraz in honey after hydrolysis to 2, 4-dimethylaniline
Shamsipur M, et al.
Journal of food composition and analysis, 21(3), 264-270 (2008)
Solid phase microextraction and gas chromatography with ion trap detector (GC-ITD) analysis of amitraz residues in beeswax after hydrolysis to 2, 4-dimethylaniline
Lenicek J, et al.
Analytica Chimica Acta, 571(1), 40-44 (2006)
Extraction and clean-up methods for the determination of amitraz total residues in beeswax by gas chromatography with electron capture detection
Jimenez JJ, et al.
Analytica Chimica Acta, 524(1-2), 271-278 (2004)
Teratogenic effects of amitraz, 2, 4-dimethylaniline, and paraquat on developing frog (Xenopus) embryos
Osano.O, et al.
Archives of Environmental Contamination and Toxicology, 43, 42-49 (2002)
Voltammetric analysis of the acaricide amitraz and its degradant, 2, 4-dimethylaniline
Brimecombe.R and Limson.J
Talanta, 71, 1298-1303 (2007)
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