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  • Carbonic anhydrase activators: activation of isozyme XIII with amino acids and amines.

Carbonic anhydrase activators: activation of isozyme XIII with amino acids and amines.

Bioorganic & medicinal chemistry letters (2006-05-30)
Seppo Parkkila, Daniela Vullo, Luca Puccetti, Anna-Kaisa Parkkila, Andrea Scozzafava, Claudiu T Supuran
ABSTRACT

The first activation study of isoform XIII of carbonic anhydrase (CA, EC 4.2.1.1) is reported. A series of amino acids and amines incorporating protonatable moieties of the primary/heterocyclic amine type were included in the study. As for CA I and II, CA XIII activators enhance kcat and show no effect on KM, for the physiologic reaction catalyzed by this isoform. Excellent CA XIII activating properties were shown by D-amino acids (His, Phe, DOPA, and Trp), serotonin, and 4-(2-aminoethyl)-morpholine, whereas the corresponding L-amino acids, dopamine, histamine, and 1-(2-aminoethyl)-piperazine, were weaker activators.

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Product Description

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