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203645

Sigma-Aldrich

Lithium fluoride

greener alternative

powder, <100 μm, ≥99.98% trace metals basis

Synonym(s):

Fluorolithium

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About This Item

Linear Formula:
LiF
CAS Number:
7789-24-4
Molecular Weight:
25.94
EC Number:
232-152-0
MDL number:
MFCD00011090
UNSPSC Code:
12352302
PubChem Substance ID:
24852188
NACRES:
NA.23

Quality Level

100

assay

≥99.98% trace metals basis

form

powder

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product, Greener Alternative Product

impurities

≤200.0 ppm Trace Metal Analysis

particle size

<100 μm

bp

1673 °C/1 atm (lit.)

mp

845 °C (lit.)

solubility

aqueous acid: slightly soluble(lit.)

density

2.64 g/mL at 25 °C (lit.)

greener alternative category

Enabling,

SMILES string

[Li+].[F-]

InChI

1S/FH.Li/h1H;/q;+1/p-1

InChI key

PQXKHYXIUOZZFA-UHFFFAOYSA-M

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General description

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Application

Lithium fluoride can be used as an electron injection layer in the fabrication of electroluminescent devices.

It can be used as an electrolyte additive to protect the lithium metal electrode, which improves the stability and reversibility of the battery. The partially soluble LiF forms a thin coating over the surface of lithium and stabilizes the SEI layer.

It can also be used as catalyst support in the preparation of carbon nanofibers by a catalytic chemical vapor deposition method.

Features and Benefits

  • High mechanical strength
  • Wide electrochemical stability window
  • Low calculated barriers toLi diffusion

pictograms

Exclamation mark
GHS07

signalword

Warning

hcodes

H302,H319

Hazard Classifications

Acute Tox. 4 Oral - Eye Irrit. 2

supp_hazards

EUH032

wgk_germany

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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(6)LiF:Mg,Cu,P and (7)LiF:Mg,Cu,P glass-rod thermoluminescent dosemeters (TLDs) were used for measurements of out-of-field photon and neutron doses produced by Varian iX linear accelerator. Both TLDs were calibrated using 18-MV X-ray beam to investigate their dose-response sensitivity and linearity. CR-39 etch-track
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