Skip to Content
MilliporeSigma
All Photos(2)

Documents

238090

Sigma-Aldrich

1-Bromo-4-iodobenzene

98%

Synonym(s):

4-Bromo-1-iodobenzene, 4-Bromoiodobenzene, 4-Iodo-1-bromobenzene, 4-Iodophenyl bromide, p-Bromophenyl iodide, p-Iodobromobenzene

Sign Into View Organizational & Contract Pricing
All Photos(2)

About This Item

Linear Formula:
BrC6H4I
CAS Number:
589-87-7
Molecular Weight:
282.90
Beilstein/REAXYS Number:
1904545
EC Number:
209-662-7
MDL number:
MFCD00001051
UNSPSC Code:
12352100
PubChem Substance ID:
24854290
NACRES:
NA.22

Quality Level

200

assay

98%

form

solid

bp

120-122 °C/14 mmHg (lit.)

mp

89-91 °C (lit.)

SMILES string

Brc1ccc(I)cc1

InChI

1S/C6H4BrI/c7-5-1-3-6(8)4-2-5/h1-4H

InChI key

UCCUXODGPMAHRL-UHFFFAOYSA-N

Looking for similar products? Visit Product Comparison Guide

Related Categories

General description

Vapour pressure as a function of temperature for 1-bromo-4-iodobenzene has been studied using a diaphragm manometer and torsion mass-loss effusion.

Application

1-Bromo-4-iodobenzene has been employed:
  • as reagent for in situ desilylation and coupling of silylated alkynes
  • as starting reagent in the total syntheses of ent-conduramine A and ent-7-deoxypancratistatin (alkaloids)
  • as substrate in copper-free Sonogashira coupling in aqueous acetone
  • in synthesis of β,β,dibromostyrenes

pictograms

Exclamation mark
GHS07

signalword

Warning

hcodes

H315,H319

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2

wgk_germany

WGK 3

ppe

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Customers Also Viewed

Slide 1 of 7

1 of 7

4-Iodoanisole 98%

Sigma-Aldrich

I7608

4-Iodoanisole

3-Chloroiodobenzene 98%

Sigma-Aldrich

242578

3-Chloroiodobenzene

(4-Bromophenylethynyl)trimethylsilane 98%

Sigma-Aldrich

494011

(4-Bromophenylethynyl)trimethylsilane

1,3-Diiodobenzene 98%

Sigma-Aldrich

475262

1,3-Diiodobenzene

4,4′-Diiodobiphenyl technical grade, 90%

Sigma-Aldrich

D122408

4,4′-Diiodobiphenyl

4-Iodobenzonitrile 97%

Sigma-Aldrich

579157

4-Iodobenzonitrile

4-Iodobenzyl bromide 95%

Sigma-Aldrich

515604

4-Iodobenzyl bromide

Representation and assessment of vapour pressure data; a novel approach applied to crystalline 1-bromo-4-chlorobenzene, 1-chloro-4-iodobenzene, and 1-bromo-4-iodobenzene.
Oonk HAJ, et al.
The Journal of Chemical Thermodynamics, 30(7), 897-907 (1998)
Synlett, 1843-1843 (2007)
Total syntheses of ent-conduramine A and ent -7-deoxypancratistatin.
Akgun H and Hudlicky T.
Tetrahedron Letters, 40(16), 3081-3084 (1999)
Synlett, 2061-2061 (2007)
Rapid bi-directional synthesis of oligo (1, 4-phenylene ethynylene) s.
Huang S and Tour JM.
Tetrahedron Letters, 40(17), 3447-3450 (1999)
View All Related Papers

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service