Skip to Content
MilliporeSigma
All Photos(1)

Documents

256021

Sigma-Aldrich

(Trimethylsilyl)methylmagnesium chloride solution

1.0 M in diethyl ether

Synonym(s):

(Trimethylsilyl)methyl magnesium chloride, Chloro(trimethylsilylmethyl)magnesium

Sign Into View Organizational & Contract Pricing


About This Item

Linear Formula:
(CH3)3SiCH2MgCl
CAS Number:
Molecular Weight:
146.97
Beilstein/REAXYS Number:
3587255
MDL number:
UNSPSC Code:
12352103
PubChem Substance ID:
NACRES:
NA.22

Quality Level

reaction suitability

reaction type: Grignard Reaction

concentration

1.0 M in diethyl ether

density

0.777 g/mL at 25 °C

SMILES string

C[Si](C)(C)C[Mg]Cl

InChI

1S/C4H11Si.ClH.Mg/c1-5(2,3)4;;/h1H2,2-4H3;1H;/q;;+1/p-1

InChI key

NAQATMJWCJCHOZ-UHFFFAOYSA-M

Looking for similar products? Visit Product Comparison Guide

Related Categories

Application

Reagent used in a variety of nickel catalyzed reactions including alkenation of dithioacetals, cross-coupling with aryl triflates and carbamates, and cross-coupling with vinyl selenides.

signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3

target_organs

Central nervous system

supp_hazards

Storage Class

4.3 - Hazardous materials, which set free flammable gases upon contact with water

wgk_germany

WGK 3

flash_point_f

-40.0 °F - closed cup

flash_point_c

-40 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Accounts of Chemical Research, 24, 257-257 (1991)
Tetrahedron Letters, 35, 6729-6729 (1994)
The Journal of Organic Chemistry, 57, 4066-4066 (1992)

Articles

We carry a large variety of electrophiles and nucleophiles that are widely used in C–C bond-forming reactions. This group of products contains many organometallic reagents as well as commonly-used alkylating and acylating reagents.

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service