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376965

Sigma-Aldrich

2,7-Di-tert-butyl-9,9-dimethylxanthene

97%

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About This Item

Empirical Formula (Hill Notation):
C23H30O
CAS Number:
130525-41-6
Molecular Weight:
322.48
MDL number:
MFCD01863485
UNSPSC Code:
12352100
PubChem Substance ID:
24863481
NACRES:
NA.22

assay

97%

mp

188-192 °C (lit.)

SMILES string

CC(C)(C)c1ccc2Oc3ccc(cc3C(C)(C)c2c1)C(C)(C)C

InChI

1S/C23H30O/c1-21(2,3)15-9-11-19-17(13-15)23(7,8)18-14-16(22(4,5)6)10-12-20(18)24-19/h9-14H,1-8H3

InChI key

COCYABCDIOEUAC-UHFFFAOYSA-N

Related Categories

General description

Synthesis of a new series of diphosphine ligands based on 2,7-di-tert-butyl-9,9-dimethylxanthene has been reported.

Application

2,7-Di-tert-butyl-9,9-dimethylxanthene may be used in the preparation of 4,5-diamino-9,9′-dimethylxanthene.

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

Certificates of Analysis (COA)

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Phenoxaphosphine-Based diphosphine ligands. synthesis and application in the hydroformylation reaction.
Zuidema E, et al.
Organometallics, 29(5), 1210-1221 (2010)
Selective acylation of 4, 5-diamino-9, 9'-dimethylxanthene through an aggregation effect.
Mu?iz FM, et al.
Tetrahedron Letters, 49(5), 790-793 (2008)
Antra Ganguly et al.
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