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Sigma-Aldrich

Lithium nitride

greener alternative

−60 mesh, ≥99.5%

Synonym(s):

Trilithium nitride

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About This Item

Linear Formula:
Li3N
CAS Number:
26134-62-3
Molecular Weight:
34.83
EC Number:
247-475-2
MDL number:
MFCD00016186
UNSPSC Code:
26111700
PubChem Substance ID:
24864824
NACRES:
NA.23

Quality Level

100

assay

≥99.5%

form

powder

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

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particle size

−60 mesh

mp

840-850 °C (N2)

density

1.3 g/mL at 25 °C (lit.)

greener alternative category

Enabling,

SMILES string

[Li]N([Li])[Li]

InChI

1S/3Li.N

InChI key

IDBFBDSKYCUNPW-UHFFFAOYSA-N

Related Categories

General description

Lithium nitride (Li3N) is a solid-state ionic conductor with an ionic conductivity of ~6 x 10−3 Scm−1 and with a high Young′s modulus. It can generally be prepared by placing Li metal under nitrogen environment.
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.

Application

Li3N can be used in a variety of applications such as a hydrogen storage material, an electron injection material for organic light-emitting diodes (OLEDs), and in the fabrication of lithium-ion batteries.

Features and Benefits

Forms high room-temperature conductivity, high lithium conduction materials with SiS2 with excellent solid electrolyte properties.

Analysis Note

Hydrogen content, XRD plots and metal purity data are available upon request.

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Interaction of nitrogen with lithium in lithium ion batteries
Wang H, et al.
Solid State Ionics, 180(2-3), 212-215 (2009)
Thermally decomposable lithium nitride as an electron injection material for highly efficient and stable OLEDs
Duan L, et al.
The Journal of Physical Chemistry C, 113(30), 13386-13390 (2009)
Joshua W Makepeace et al.
Physical chemistry chemical physics : PCCP, 20(35), 22689-22697 (2018-08-24)
Lithium imide is a promising new catalyst for the production of hydrogen from ammonia. Its catalytic activity has been reported to be significantly enhanced through its use as a composite with various transition metal nitrides. In this work, two of
D Muller-Bouvet et al.
Physical chemistry chemical physics : PCCP, 19(40), 27204-27211 (2017-10-04)
A large data set of XAS (X-ray Absorption Spectroscopy) Manganese K-edge spectra has been collected operando and studied upon the electrochemical oxidation of the promising Li-ion battery anode material Li

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