Skip to Content
MilliporeSigma
All Photos(5)

Documents

459925

Sigma-Aldrich

Platinum(IV) oxide

greener alternative

Synonym(s):

Adam’s catalyst, NSC 402624, Platinic oxide, Platinum dioxide

Sign Into View Organizational & Contract Pricing
All Photos(5)

About This Item

Linear Formula:
PtO2
CAS Number:
1314-15-4
Molecular Weight:
227.08
EC Number:
215-223-0
MDL number:
MFCD00011184
UNSPSC Code:
12352300
PubChem Substance ID:
24869619
NACRES:
NA.22

form

solid

Quality Level

200

composition

Pt, 79-83%

reaction suitability

core: platinum
reagent type: catalyst

greener alternative product characteristics

Designing Safer Chemicals
Catalysis
Learn more about the Principles of Green Chemistry.

surface area

≥75 m2/g

impurities

iron, low

mp

450 °C (lit.)

greener alternative category

Aligned,

SMILES string

O=[Pt]=O

InChI

1S/2O.Pt

InChI key

YKIOKAURTKXMSB-UHFFFAOYSA-N

Looking for similar products? Visit Product Comparison Guide

Related Categories

General description

Prepared by Adams′ nitrate fusion method.
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

Application

Catalyst for:
  • Hydrohydrazination reactions
  • Oxidation of sugars
  • Low-temperature oxidation of carbon monoxide
  • Oxygen reduction reaction
  • Hydrogenation reactions
  • Hydrogenolysis of the cyclopropyl group into an isopropyl group
  • Hydroxycyclopropanation reactions
Catalyst for hydrogenation of various functional groups; used as dehydrogenation catalyst; used for selective oxidation of primary alcohols.

pictograms

Flame over circle
GHS03

signalword

Danger

hcodes

H271

Hazard Classifications

Ox. Sol. 1

Storage Class

5.1A - Strongly oxidizing hazardous materials

wgk_germany

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Customers Also Viewed

Slide 1 of 8

1 of 8

Palladium hydroxide on carbon extent of labeling: 20 wt. % loading (dry basis), matrix carbon, wet support

Sigma-Aldrich

212911

Palladium hydroxide on carbon

Iridium(IV) oxide 99.9% trace metals basis

Sigma-Aldrich

206237

Iridium(IV) oxide

Palladium hydroxide on carbon extent of labeling: 20 wt. % loading (dry basis), matrix carbon, wet support

Sigma-Aldrich

330094

Palladium hydroxide on carbon

[Pd(OAc)2]3 99.98% trace metals basis

Sigma-Aldrich

379875

[Pd(OAc)2]3

Bromoacetonitrile 97%

Sigma-Aldrich

242489

Bromoacetonitrile

Diphenyl phosphoryl chloride 99%

Sigma-Aldrich

D206555

Diphenyl phosphoryl chloride

Lithium bis(trimethylsilyl)amide solution 1.0 M in THF

Sigma-Aldrich

225770

Lithium bis(trimethylsilyl)amide solution

Palladium on carbon extent of labeling: 10 wt. % loading, matrix activated carbon support

Sigma-Aldrich

205699

Palladium on carbon

Development of GSKDevelopment of GSK's reagent guides ? embedding sustainability into reagent selections reagent guides ? embedding sustainability into reagent selection.
Adams JP, et al.
Green Chemistry, 15, 1542-1549 (2013)

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service