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Sigma-Aldrich

Halloysite nanoclay

Synonym(s):

Kaolin clay

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About This Item

Linear Formula:
Al2Si2O5(OH)4 · 2 H2O
CAS Number:
Molecular Weight:
294.19
EC Number:
MDL number:
UNSPSC Code:
12162002
PubChem Substance ID:
NACRES:
NA.23

form

nanopowder

Quality Level

diam. × L

30-70 nm × 1-3 μm , nanotube

surface area

64 m2/g

color

75-96, Hunter Brightness

refractive index

n20/D 1.54

pore size

1.26-1.34 mL/g pore volume

capacity

8.0 meq/g cation exchange capacity

density

2.53 (true specific gravity)

SMILES string

O.O.O[Si](O)(O[Al]=O)O[Si](O)(O)O[Al]=O

InChI

1S/2Al.H4O7Si2.2H2O.2O/c;;1-8(2,3)7-9(4,5)6;;;;/h;;1-2,4-5H;2*1H2;;/q2*+1;-2;;;;

InChI key

HEFIDAICLOZRRO-UHFFFAOYSA-N

General description

Halloysite nanoclay has a tube like morphology. It shows low electrical, thermal conductivity and strong hydrogen interactions, on account of which the inner hydroxyl groups show greater stability than the surface hydroxyl groups in halloysite. The loss of hole water occurs at nearly 300 °C.
Similar to montmorillonite, halloysite consists of two layers of aluminosilicate in 1:1 Al:Si ratio. Significant improvements in thermal, mechanical properties have been reported on addition of halloysite nanotubes in polymer composites.

Application

Halloysite is frequently used as a reinforcement in various nanocomposites, some of which are listed here:
Isotactic propylene-halloysite nanocomposites.
Alloy composites by electroless/ autocatalytic deposition.
Poly(butylene terephthalate) (PBT) composites.
Zinc–halloysite nanotube (HNT) composite coatings.
Halloysite nanotube–hydroxyapatite–hyaluronic acid films.
Halloysite combined with polyamide, polypropylene, poly(ε-caprolactone) and fluroelastomers.
Its tube like morphology, high aspect ratio, and low percolation enables interesting applications as reinforcements in nanocomposites.

Legal Information

Product of Applied Minerals, Inc. Customers may obtain additional technical support and purchase commercial quantities at appliedminerals.com

wgk_germany

nwg

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)


Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Effects of filler type on the nonisothermal crystallization kinetics of poly(butylene terephthalate) (PBT) composites
Oburo?lu N, et al.
Journal of Applied Polymer Science, 123(1), 77-91 (2012)
Joussein E. et al.
Clay Minerals, 40, 383-383 (2005)
Electrophoretic deposition of composite halloysite nanotube?hydroxyapatite?hyaluronic acid films
Deen I and Zhitomirsky I
J. Alloy Compounds, 586(1), S531-S534 (2014)
Vladimir Vinokurov et al.
Polymers, 11(5) (2019-05-30)
Silica gels are widely employed in water shutoff services, making them an essential tool in oil well management. Silica nanoparticles may serve as a strengthening additive for polymer hydrogels. In this study, we look at this statement from a different
S R Levis et al.
International journal of pharmaceutics, 243(1-2), 125-134 (2002-08-15)
Halloysite supplied from New Zealand was shown by electron microscopy to be composed mainly of hollow microtubules having typical dimensions of 2-3 microm long and 0.3/0.1 microm outer/inner diameter. Aggregates of microtubules, double tubules and occasional split or partially unrolled

Articles

Halloysite Nanotubes in Nanomaterials Research. Halloysite, a naturally occurring aluminosilicate nanotube, has been undeservedly forgotten.

Nanoclays are nanoparticles of layered mineral silicates. Montmorillonite, bentonite, and halloysite nanoclays and organoclays are used in polymer-clay nanocomposites, as rheology modifiers, and drug delivery carriers.

Graphene is a one-atomic-layer thick two-dimensional material made of carbon atoms arranged in a honeycomb structure. Its fascinating electrical, optical, and mechanical properties ignited enormous interdisciplinary interest from the physics, chemistry, and materials science fields.

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

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