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923451

Sigma-Aldrich

(PhMPhos)PdCl2

1:1 complex with CH2Cl2

Synonym(s):

1-Diadamantylphosphino-1′-diphenylphosphinoferrocene palladium dichloride

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About This Item

Empirical Formula (Hill Notation):
C42H48Cl2FeP2Pd
Molecular Weight:
847.95
UNSPSC Code:
12352101
NACRES:
NA.21

Quality Level

form

powder

reaction suitability

reagent type: catalyst
reaction type: Cross Couplings

Application

(PhMPhos)PdCl2 is an unsymmetrical ferrocene-based Pd-catalyst. The MPhos series of ligands are unsymmetrical diphosphino-ferrocenes bearing a bulky adamantyl group. (PhMPhos)PdCl2 can be used for a variety of cross-coupling transformations, including Suzuki coupling, C-P coupling, and Csp2-Csp3 coupling. Demonstrated Csp2-Csp3 couplings include Murahashi-Feringa Coupling (Alkyl-Li), Kumada-Corriu coupling (Alkyl-MgX), Negishi coupling (Alkyl-ZnX) and Suzuki–Miyaura coupling (Alkyl-B(OR2)).

Learn more about MPhos ligands and catalysts

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Hazard Classifications

Carc. 2 - Eye Irrit. 2 - Skin Irrit. 2

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WGK 3

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Not applicable

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Not applicable


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