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CF0002

Sigma-Aldrich

1-Fluoro-3,3-dimethylbenziodoxole

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About This Item

Linear Formula:
C9H10FIO
CAS Number:
1391728-13-4
MDL number:
MFCD28397076
UNSPSC Code:
12352101
NACRES:
NA.22

form

solid

reaction suitability

reaction type: C-C Bond Formation

InChI

1S/C9H10FIO/c1-9(2)7-5-3-4-6-8(7)11(10)12-9/h3-6H,1-2H3

InChI key

FISITPXJYDTLHI-UHFFFAOYSA-N

Related Categories

Application

1-Fluoro-3,3-dimethylbenziodoxole is a crystalline, off-white solid which can be handled under air for extended periods without noticeable hydrolytic decomposition. In the presence of excess fluoride ions (provided by triethylamine-hydrogen fluoride complexes), it can effectively function as an electrophilic fluorination reagent for easily enolizable diketo substrates, or it can engage in silver catalyzed difluorination of styrenes.

Automate your fluorination reactions with Synple Automated Synthesis Platform (SYNPLE-SC002)

Other Notes

Technology Spotlight: Fluoroalkylation: Expansion of Togni Reagents

Legal Information

Product of CF Plus Chemicals.

pictograms

Flame over circle
GHS03

signalword

Danger

hcodes

H272

pcodes

P210

Hazard Classifications

Ox. Sol. 2

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Articles

Fluoroalkylation: Expansion of Togni Reagents

The fluoroalkylation toolbox now includes Togni reagents, hypervalent iodine perfluoroalkylation reagents, fluoroalkyl bromides, silanes, carboxylates, and sulfonyl fluorides for late stage fluoroalkylation.

Fluoroalkylation: Expansion of Togni Reagents

The fluoroalkylation toolbox now includes Togni reagents, hypervalent iodine perfluoroalkylation reagents, fluoroalkyl bromides, silanes, carboxylates, and sulfonyl fluorides for late stage fluoroalkylation.

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