8.18737
Chlorotrimethylsilane
for synthesis
Synonym(s):
Chlorotrimethylsilane, Trimethylchlorosilane, Trimethylsilyl chloride, TMCS
About This Item
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vapor pressure
250 hPa ( 20 °C)
Quality Level
assay
≥99.0% (GC)
form
liquid
autoignition temp.
420 °C
potency
4868 mg/kg LD50, oral (Rat)
1530 mg/kg LD50, skin (Rabbit)
expl. lim.
1.5-46 % (v/v)
bp
57 °C/1013 hPa
mp
-58 °C
transition temp
flash point -20 °C
density
0.86 g/cm3 at 20 °C
storage temp.
2-30°C
InChI
1S/C3H9ClSi/c1-5(2,3)4/h1-3H3
InChI key
IJOOHPMOJXWVHK-UHFFFAOYSA-N
Related Categories
Application
- Synthesis of bis ferrocene derivatives: Development of new ferrocenyl multi-functional silyl ether compounds using chlorotrimethylsilane, highlighting advances in organosilicon chemistry (R Teimuri-Mofrad et al., 2016).
- Pharmacologically active derivatives: Use of chlorotrimethylsilane as a catalyst in the synthesis of pharmacologically active bis (indolyl) and tris (indolyl) derivatives, demonstrating its efficiency in electrophilic substitution reactions (NG Singh et al., 2014).
- Silicone resin synthesis: Exploration of the hydrolysis-condensation reaction of tetraethoxysilane and chlorotrimethylsilane to create silicone resins, showing the material′s enhanced properties for industrial applications (CFJ Kuo et al., 2014).
- Deoxygenation of unsymmetrical dicarbonyl compounds: Innovative use of chlorotrimethylsilane and sodium iodide for the selective reduction of 1,2-diketones, showcasing a novel method in organic synthesis (LZ Yuan et al., 2016).
- Enhanced activity and durability of catalysts: Investigation into Fe3+ and chlorotrimethylsilane modified NaY catalysts for the acetalization of glycerol to solketal, improving catalytic performance in chemical processes (Y Li et al., 2023).
Analysis Note
Density (d 20 °C/ 4 °C): 0.858 - 0.861
Identity (IR): passes test
signalword
Danger
Hazard Classifications
Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Acute Tox. 4 Dermal - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1A
supp_hazards
Storage Class
3 - Flammable liquids
wgk_germany
WGK 1
flash_point_f
-18.4 °F - closed cup
flash_point_c
-28 °C - closed cup
Certificates of Analysis (COA)
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