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86833

Sigma-Aldrich

Tetrabutylammonium phosphate monobasic

puriss., 99% (T)

Synonym(s):

Tetrabutylammonium dihydrogen phosphate

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About This Item

Linear Formula:
(CH3CH2CH2CH2)4N[OP(OH)2O]
CAS Number:
5574-97-0
Molecular Weight:
339.45
Beilstein/REAXYS Number:
5196532
EC Number:
226-947-1
MDL number:
MFCD00064526
UNSPSC Code:
12352116
PubChem Substance ID:
329769489

grade

puriss.

Quality Level

100

assay

99% (T)

form

powder

mp

151-154 °C (lit.)

SMILES string

OP(O)([O-])=O.CCCC[N+](CCCC)(CCCC)CCCC

InChI

1S/C16H36N.H3O4P/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;1-5(2,3)4/h5-16H2,1-4H3;(H3,1,2,3,4)/q+1;/p-1

InChI key

ARRNBPCNZJXHRJ-UHFFFAOYSA-M

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General description

Tetrabutylammonium phosphate monobasic is a synthetic reagent. It can serve as a pH buffer in various chemical and biological applications.

Application

Tetrabutylammonium phosphate monobasic is the suitable reagent used in the following studies:
  • Resolution of disaccharides reverse-phase ion-pairing HPLC (RPIP-HPLC).
  • Disaccharide analysis of 35S- heparan sulfate (HS).
  • As folding buffer for the dissolution of desalted oligonucleotides.
It may be used as reagent for the analysis of tetrasaccharides and 35S-disaccharides by HPLC. It may also be used in the preparation of monobasic tetrabutylammonium phosphate (TBAP) imprinted polymers.

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

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The Journal of biological chemistry, 274(53), 38155-38162 (1999-12-23)
3-O-Sulfation of glucosamine by heparan sulfate D-glucosaminyl 3-O-sulfotransferase (3-OST-1) is the key modification in anticoagulant heparan sulfate synthesis. However, the heparan sulfates modified by 3-OST-2 and 3-OST-3A, isoforms of 3-OST-1, do not have anticoagulant activity, although these isoforms transfer sulfate
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The Journal of biological chemistry, 277(40), 37912-37919 (2002-07-26)
Heparan sulfate 3-O-sulfotransferase transfers sulfate to the 3-OH position of a glucosamine residue of heparan sulfate (HS) to form 3-O-sulfated HS. The 3-O-sulfated glucosamine residue contributes to two important biological functions of HS: binding to antithrombin and thereby carrying anticoagulant
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