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Tetrabutylammonium perchlorate

for electrochemical analysis, ≥99.0%

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About This Item

Linear Formula:
(CH3CH2CH2CH2)4N(ClO4)
CAS Number:
1923-70-2
Molecular Weight:
341.91
Beilstein/REAXYS Number:
3579274
EC Number:
217-655-5
MDL number:
MFCD00038722
UNSPSC Code:
26111700
PubChem Substance ID:
329769341

grade

for electrochemical analysis

Quality Level

100

assay

≥99.0% (T)
≥99.0%

form

powder

mp

211-215 °C

solubility

acetonitrile: 0.1 g/mL, clear, colorless

SMILES string

[O-]Cl(=O)(=O)=O.CCCC[N+](CCCC)(CCCC)CCCC

InChI

1S/C16H36N.ClHO4/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;2-1(3,4)5/h5-16H2,1-4H3;(H,2,3,4,5)/q+1;/p-1

InChI key

KBLZDCFTQSIIOH-UHFFFAOYSA-M

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General description

Tetrabutylammonium perchlorate (TBAP) is a quaternary ammonium salt, mainly used as electrolyte.
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Application

TBAP has been used as solvent in preparing standard stock solutions, for HPLC analysis of Sudan azo-dyes food samples. It may be used as an electrophoretic buffer to rinse the capillary for the nonaqueous capillary electrophoresis (NACE) determination of atropine, anisodamine, and scopolamine in Flos daturae plant extract.

pictograms

Flame over circleExclamation mark
GHS03,GHS07

signalword

Danger

Hazard Classifications

Eye Irrit. 2 - Ox. Sol. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

5.1B - Oxidizing hazardous materials

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges

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Certificates of Analysis (COA)

Lot/Batch Number
BCCC3465
BCBV2001
BCBQ2776V
BCBM0840V
BCBG9625V

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Sigma-Aldrich

86888

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Tetrabutylammonium perrhenate 98%

Sigma-Aldrich

250228

Tetrabutylammonium perrhenate

Simultaneous determination of atropine, anisodamine, and scopolamine in plant extract by nonaqueous capillary electrophoresis coupled with electrochemiluminescence and electrochemistry dual detection.
Yuan B
Journal of Chromatography A, 1217(1), 171-174 (2010)
Analysis of sudan I, sudan II, sudan III, and sudan IV in food by HPLC with electrochemical detection: Comparison of glassy carbon electrode with carbon nanotube-ionic liquid gel modified electrode.
Chailapakul O
Food Chemistry, 109(4), 876-882 (2008)
David Balcells et al.
Dalton transactions (Cambridge, England : 2003), (30)(30), 5989-6000 (2009-07-23)
Experimental studies have shown that the C-H oxidation of Ibuprofen and methylcyclohexane acetic acid can be carried out with high selectivities using [(terpy')Mn(OH(2))(mu-O)(2)Mn(OH(2))(terpy')](3+) as catalyst, where terpy' is a terpyridine ligand functionalized with a phenylene linker and a Kemp's triacid
Benjamin T Diroll et al.
Nature communications, 10(1), 4511-4511 (2019-10-06)
Colloidal quantum wells are two-dimensional materials grown with atomically-precise thickness that dictates their electronic structure. Although intersubband absorption in epitaxial quantum wells is well-known, analogous observations in non-epitaxial two-dimensional materials are sparse. Here we show that CdSe nanoplatelet quantum wells
Atanu Jana et al.
Dalton transactions (Cambridge, England : 2003), 44(1), 359-367 (2014-11-11)
A novel electron rich, tetrathiafulvalene fused zinc porphyrin, (TTF)4PZn, has been newly synthesized and characterized using spectral and electrochemical methods. In spite of the presence of eight t-butyl groups, (TTF)4PZn exhibited appreciable aggregation in solution. Scanning electron microscopic (SEM) imaging
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