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124060

Sigma-Aldrich

2-Bromofluorene

95%

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About This Item

Empirical Formula (Hill Notation):
C13H9Br
CAS Number:
Molecular Weight:
245.11
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

Quality Level

assay

95%

bp

185 °C/135 mmHg (lit.)

mp

112-114 °C (lit.)

SMILES string

Brc1ccc-2c(Cc3ccccc-23)c1

InChI

1S/C13H9Br/c14-11-5-6-13-10(8-11)7-9-3-1-2-4-12(9)13/h1-6,8H,7H2

InChI key

FXSCJZNMWILAJO-UHFFFAOYSA-N

General description

2-Bromofluorene is a nonintrusive end-capping reagent to control molecular weights and to generate well-defined oligomers.

Application

2-Bromofluorene was used in the synthesis of end-capping reagent 2-bromo-9,9-di-nhexylfluorene. It has been used in the preparation of poly(di-n-hexylfluorene)s end capped with 2-bromofluorene, 2-bromo-9,9-di-n-hexylfluorene and 9-bromoanthracene through Ni(0) mediated polymerization. It was also used in the synthesis of 2-bromo-9,9-dihexylfluorene.

pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves


Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Polyfluorene derivatives: effective conjugation lengths from well-defined oligomers.
Klaerner G and Miller RD.
Macromolecules, 31(6), 2007-2009 (1998)
Well-defined [3, 3'] bicarbazolyl-based electroactive compounds for optoelectronics.
Vaitkeviciene V, et al.
Synthetic Metals, 158(8), 383-390 (2008)
Tetrahedron Letters, 48, 89-89 (2007)
Tetrahedron Letters, 47, 7085-7085 (2006)
Excimer and Aggregate Formations in Poly (fluorene) s.
Lee JI, et al.
ETRI Journal, 24(6), 409-414 (2002)

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