Skip to Content
MilliporeSigma
All Photos(1)

Documents

380768

Sigma-Aldrich

Potassium diphenylphosphide solution

0.5 M in THF

Synonym(s):

Potassium diphenylphosphine, Diphenylphosphine potassium salt, KPPh2

Sign Into View Organizational & Contract Pricing


About This Item

Linear Formula:
(C6H5)2PK
CAS Number:
Molecular Weight:
224.28
Beilstein/REAXYS Number:
4164304
MDL number:
UNSPSC Code:
12352002
PubChem Substance ID:
NACRES:
NA.22

form

liquid

Quality Level

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand

concentration

0.5 M in THF

density

0.929 g/mL at 25 °C

functional group

phosphine

SMILES string

[K]P(c1ccccc1)c2ccccc2

InChI

1S/C12H10P.K/c1-3-7-11(8-4-1)13-12-9-5-2-6-10-12;/h1-10H;/q-1;+1

InChI key

FCLYZQXPJKJTDR-UHFFFAOYSA-N

Looking for similar products? Visit Product Comparison Guide

Related Categories

Application


  • Synthesis, reactivity and molecular structure of phosphino tetramethyl cyclopentadienyl complex (eta5: eta1-C5Me4CH2PPh2)Re(CO)2.: This study explores the synthesis and reactivity of a novel phosphino complex, utilizing Potassium diphenylphosphide as a key reagent. The research highlights the molecular structure and potential applications in organometallic chemistry (Godoy et al., 2009).

  • Improved and efficient synthesis of chiral N,P-ligands via cyclic sulfamidates for asymmetric addition of butyllithium to benzaldehyde.: This paper details an improved synthesis method for chiral N,P-ligands using Potassium diphenylphosphide. The research demonstrates the compound′s efficacy in asymmetric synthesis, offering potential advancements in drug discovery and development (Rönnholm et al., 2007).

  • Coordination chemistry of diselenophosphinate complexes: the X-ray single-crystal structures of [K(Se2PPh2)(THF)2]2 and [In(Se2PPh2)3].L (L = THF, PhMe).: This article investigates the coordination chemistry involving diselenophosphinate complexes, with Potassium diphenylphosphide playing a crucial role. The study provides detailed X-ray crystallographic data, offering insights for future research in chemical synthesis and materials science (Davies et al., 2004).


signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Carc. 2 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3

target_organs

Respiratory system

supp_hazards

wgk_germany

WGK 3

flash_point_f

-4.0 °F

flash_point_c

-20 °C

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Customers Also Viewed

Slide 1 of 5

1 of 5

2-Fluoroaniline ≥99%

Supelco

F3401

2-Fluoroaniline

Potassium hydride in paraffin

Sigma-Aldrich

708860

Potassium hydride

[Pd(OAc)2]3 reagent grade, 98%

Sigma-Aldrich

205869

[Pd(OAc)2]3

2,6-Dibromopyridine 98%

Sigma-Aldrich

D43115

2,6-Dibromopyridine

Synlett, 509-509 (1993)
The Journal of Organic Chemistry, 58, 5832-5832 (1993)
Tetrahedron, 50, 799-799 (1994)
Organometallics, 13, 2928-2928 (1994)

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service