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930105

Sigma-Aldrich

S-(4-nitrophenyl) methanethioate

≥95%

Synonym(s):

p-NO2-phenyl thioCORMate, p-NO2-phenyl thioformate

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About This Item

Empirical Formula (Hill Notation):
C7H5NO3S
CAS Number:
Molecular Weight:
183.18
UNSPSC Code:
12352101
NACRES:
NA.06

Quality Level

assay

≥95%

form

powder

reaction suitability

reaction type: C-C Bond Formation

storage temp.

2-8°C

SMILES string

[H]C(SC1=CC=C([N+]([O-])=O)C=C1)=O

Related Categories

Application

S-(4-nitrophenyl) methanethioate is an effective CO releasing molecule (CORM) developed by the lab of Sarah Tasker as part of a series of thioformate based CORMs called thioCORMates. p-NO2 phenyl thioformate generates CO rapidly for faster reactions that require instantaneous on-demand generation of CO. using only a simple amine to activate it.

This and the other thioCORMates are cost effective CORMs that when activated with simple amines, can be used to generate a near quantitative amount of CO safely without the usage of gas cylinders. These are compatible with a variety of carbonylation reactions, as well as existing COware glassware and components.

ThioCORMate: Tunable and Cost-Effective Carbon Monoxide-Releasing Molecule

Learn more about CO releasing molecules from Prof. Skrydstrup

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable


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